Product ID:METHANOL, 9076
MSDS Date:05/01/1989
FSC:6810
NIIN:00N023130
MSDS Number: BLXCR

J T BAKER INC

222 RED SCHOOL LANE
PHILLIPSBURG, NJ 08865
US

Emergency Phone: 201-859-2151;800-424-9300(CHEMTREC)

Info Phone: 201-859-2151

Preparer: QUALITY ASSURANCE DEPT

Cage: DO803

MALLINCKRODT BAKER, INC.

PHILLIPSBURG, NJ 08865 US

Telephone: 800-582-2537

Cage: 70829

METHANOL; (METHYL ALCOHOL)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 90-100%

OSHA PEL S,200PPM/250STEL

ACGIH TLV: S,200PPM/250STEL; 93

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:LD50:(ORAL,RAT) 5628 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL: HARMFUL & MAY BE FATAL,
HEADACHE, NAUSEA, VOMITING, DIZZINESS, NARCOSIS, RESPIRATORY
FAILURE, LOW BLOOD PRESSURE, CENTRAL NERVOUS SYSTEM DEPRESSION.
SKIN: IRRITATION, PROLONGED CONTACT MAY CAUS E DERMATITIS. EYE:
IRRITATION, MAY CAUSE TEMPORARY CORNEAL DAMAGE. INGEST: HARMFUL &
MAY BE FATAL, (SEE EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: BLINDNESS, HEADACHE, NAUSEA,
VOMITING, DIZZINESS, GASTROINTESTINAL IRRITATION, CENTRAL NERVOUS
SYSTEM DEPRESSION, HEARING LOSS. CHRONIC: KIDNEY & LIVER DAMAGE.
TARGET ORGANS: EYES, SKIN, CEN TRAL NERVOUS SYSTEM, GI TRACT,
RESPIRATORY SYSTEM, LUNGS.
Medical Cond Aggravated by Exposure:EYE DISORDERS, SKIN DISORDERS,
LIVER OR KIDNEY DISORDERS.

First Aid:INGEST: CALL MD. IF CONSCIOUS, GIVE LG AMTS OF WATER. INDUCE
VOMITING. INHAL: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTF
RESP. IF BREATHING DIFFICULT, GIVE O*2. SKIN: IMMEDIATELY FLUSH
WITH PLEN TY OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING
CONTAMINATED CLOTHING AND SHOES. WASH CLOTHING BEFORE RE-USE. EYE:
IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES.

Flash Point Method:CC
Flash Point:54.0F,12.2C
Lower Limits:6%
Upper Limits:36%
Extinguishing Media:USE ALCOHOL FOAM, DRY CHEMICAL OR CO*2. (WATER MAY
BE INEFFECTIVE).
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. MOVE CNTNRS FROM FIRE AREA IF CAN BE DONE W/O RISK. USE WATER TO
KEEP FIRE-EXPOSED CNTNRS COOL.
Unusual Fire/Explosion Hazard:VAPS MAY FLOW ALONG SURFS TO DISTANT
IGNIT SOURCES & FLASH BACK. CLOSED CNTNRS EXPOSED TO HEAT MAY
EXPLODE. CONT W/STRONG OXIDIZERS MAY CAUSE FIRE.(SUPP DATA)

Spill Release Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT CLTHG.
SHUT OFF IGNIT SOURCES; NO FLARES, SMOKING/FLAMES IN AREA. STOP
LEAK IF CAN DO SO W/O RISK. USE WATER SPRAY TO REDUCE VAPS. TAKE UP
W/SAND/OTHER NON-COMB UST ABSORB MATL & PLACE INTO CNTNR FOR (SUPP
DATA)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. STORE
IN COOL, DRY, WELL-VENTILATED, FLAMMABLE LIQUID STORAGE AREA.
Other Precautions:BOND & GROUND CNTNRS WHEN TRANSFERRING LIQ. FLAMM.
CANNOT BE MADE NON-POISONOUS. KEEP AWAY FROM HEAT, SPARKS, FLAME.
DO NOT GET IN EYES, ON SKIN/CLTHG. AVOID BREATHING VAPOR. USE WITH
ADEQUATE VENTILA TION.

Respiratory Protection:RESPIRATORY PROTECTION REQUIRED IF AIRBORNE
CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS ABOVE 200 PPM, A
NIOSH/MSHA APPROVED SCBA IS ADVISED.
Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV
REQUIREMENTS.
Protective Gloves:RUBBER GLOVES RECOMMENDED.
Eye Protection:CHEM WORK GOG & FULL LENGTH FSHLD.
Other Protective Equipment:UNIFORM AND PROTECTIVE SUIT.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
EXPLO HAZ: BURNS WITH CLEAR, ALMOST INVISIBLE FLAME. SPILL PROC: LATER
DISPOSAL. FLUSH AREA WITH WATER. J T BAKER SOLUSORB(R) SOLVENT
ABSORBENT IS RECOMMENDED FOR SPILLS OF THIS PRODUCT.

HCC:F5
Boiling Pt:B.P. Text:149F,65C
Melt/Freeze Pt:M.P/F.P Text:-144F,-98C
Vapor Pres:96 @ 20C
Vapor Density:1.11
Spec Gravity:0.79
Evaporation Rate & Reference:4.6 (BUTYL ACETATE = 1)
Solubility in Water:COMPLETE (100%)
Appearance and Odor:CLEAR, COLORLESS LIQUID, PUNGENT ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG ACIDS, ZINC, ALUMINUM, MAGNESIUM.
Stability Condition to Avoid:HEAT, FLAME, OTHER SOURCES OF IGNITION.
Hazardous Decomposition Products:CO, CO*2, FORMALDEHYDE.

Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS. EPA HAZ WASTE
#U154.

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